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以下因為這次忘記拍照，先用一些示意圖，等之後修理其他支的機會，再來補照片
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These attributes can Enhance the fire resistance and char development of polyamide during the combustion procedure owing for their precise flame retardant system [nine]. On the other hand, the lower degradation temperature from the elementary substance in phosphorus-kind flame retardants limits their application inside the processing of polyamide [10].
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The microstructure analyze with the HCNP and char levels fashioned in the course of the combustion while in the cone calorimetry test was carried out using the scanning electron microscope ZEISS Sigma HDTM. Photographs have been attained less than vacuum in a voltage of five kV.
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Due to exceptional normal flame retardant synergies and thermal steadiness of polyphosphazene, it really is thought that an more and more significant job will likely be played by polyphosphazene modified with nanoparticles in flame retardant programs. By way of example, polyphosphazene loading with MoS2 nanosheets has been efficiently fabricated and significantly improved the flame retardancy of epoxy resin, i.
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Regarding the TGA outcomes of FR-PA66, the Tmax1 slowly shifted into a reduce temperature than that in the neat PA66 with raising HCNP as a result of low Ti of pure HCNP. Determine 1c demonstrates which the Ti of HCNP is 352 °C because of the P-N bond priority breakage between HCCP and DABA beneath decreased temperatures. It is exciting to discover which the P-that contains alkanes of FR-PA66 are detected through the TG-IR take a look at underneath 400 °C, that's considerably distinct with the thermal decomposition solutions of pure PA66 [twenty]. Furthermore, the R-P· radicals made by HCNP can catalyze and accelerate the breaking of C-N bonds on the α position in the PA66 molecular chain, resulting in the formation of unstable amino radicals and carbonyl radicals, bringing about the tga66 decomposition with the FR-PA66.